Asymmetric Top Molecules. Part 2 by W. Hüttner, J. Demaison, J. Vogt (auth.), W. Hüttner (eds.)

By W. Hüttner, J. Demaison, J. Vogt (auth.), W. Hüttner (eds.)

Volume II/29 "Molecular Constants commonly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy" is deliberate to seem as a chain A, B, C and D1, D2, D3 for the diamagnetic, and E for the paramagnetic linear and polyatomic species, respectively. Like within the preseding volumes II/24 and II/19, that have seemed within the years round 1999 and 1992, respectively, the diamagnetic elements are prepared within the demeanour advised via Hill ("Hill's system", 1900), that means a virtually strict alphabetical order. The ionic species are incorporated within the alphabetical association of the impartial ones in every one desk. the data is grouped another way compared to the former volumes. All proper houses of a molecule and the corresponding parameters are available focused less than its sum formulation in quantity II/29. this diminishes the necessity of turning pages simply because rotational and comparable constants, dipole moments, limitations to inner rotation, hyperfine coupling parameters, or Zeeman facts have been hitherto indexed in several tables. the current subvolume II/29D2 comprises facts for uneven most sensible molecules.

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J. Chem. Phys. 109 (1998) 5383. : Mol. Phys. 102 (2004) 1569. : J. Mol. Spectrosc. 229 (2005) 244.

Chem. Ref. 6, 2008. 3 Internal rotation [Ref. p. 1 Hamiltonian The rotational spectrum of a molecule with internal rotation (torsion) is modified due to torsion-rotation interaction. The interpretation of this modification allows the determination of the internal rotation potential barrier [59Lin, 68Dre, 84Gor]. The molecule is generally taken to be rigid except for internal rotation. However, special methods have been developed to include the interaction with other vibrational degrees of freedom.

Rev. Mod. Phys. 31 (1959) 841. : Tables for the Internal Rotation Problem, Notre Dame University, Indiana, Department of Chemistry, 1961. : J. Mol. Spectrosc. 21 (1966) 4. : Rotational Spectra and Molecular Structure, New York: Academic Press, 1967. : J. Mol. Spectrosc. 22 (1967) 49. : Fortschr. Chem. Forsch. 10 (1968) 59. : 2A Rotational spectra of molecules with two internal degrees of freedom, in: Molecular Spectroscopy: Modern Research, New York and London: Academic Press, 1972, p. 59. : J.

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